Spectres de masse d'hydrazino-2 benzo- et naphtothiazoles et d'hydrazones des méthyl-3 benzo- et naphtothiazolinones-2

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Abstract
Electron impact mass spectra are reported for the hydrazones of 3-methyl-2-benzothiazolinone (1), of 4-, 5-, 6-, and 7-chloro-3-methylbenzo-2-thiazolinones (2, 3, 4, and 5) and of 3-methyl-naphtho[2,1-d]-2-thiazolinone (6), as well as for 2-hydrazinobenzothiazole (7), for 4-, 5-, 6-, and 7-chloro-2-hydrazinobenzothiazoles (8, 9, 10, and 11) and for 2-hydrazinonaphtho[2,1-d]thiazole (12). The results obtained in the two series are compared. The 2-hydrazone and 3-methyl-benzo-2-thiazolinone and its derivatives all form a base peak corresponding to the molecular ion; fragmentation proceeds mainly by successive losses of·NH2, HCN, HCN, and then CS. Initial losses of N2H2, NH·, and NH3 are minor fragmentation routes.In the case of 2-hydrazinobenzothiazole and its derivatives, the base peak is still that of the molecular ion; however, the relative proportions of the various fragment ions vary with the position of sampling probe inside the apparatus. Thus it is concluded that the observed mass spectrum is that of a mixture of the possible hydrazone-hydrazine tautomers. The principal fragmentations involve the initial loss of NH3 (leading to a stabilized ion), of NH2· (probably from the hydrazone form), and of N2H2.(Journal Translation)

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