Liquid crystalline behaviour of hydrogen bonded complexes of a non-mesogenic anil with p-n-alkoxybenzoic acids

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Abstract
Phase diagrams of binary mixtures of the non-mesogenic N -(p -methoxy- o -hydroxybenzylidbe ene)- p -aminopyridine with a series of p - n -alkoxybenzoic acids ranging from methoxy to hexadecyloxy were established using differential scanning calorimetry and polarising optical microscopy. The key results obtained are: (1) the formation of 1 1 hydrogen bonded complexes between the pyridine derivative and the alkoxybenzoic acids, (2) the stability of the alkoxybenzoic acid mesophases over a wide range of compositions (up to slightly over 50 mol% of the pyridine derivative), (3) the absence of additional mesophases corresponding specifically to the 1 1 complexes, and (4) the complete miscibility of the acids with the complexes in the mesomorphic state. With alkoxy chains from methoxy to heptyloxy, mixtures produce only nematic phases; they produce both nematic and smectic phases with chains from octyloxy to dodecyloxy, and only smectic phases with chains from tetradecyloxy to hexadecyloxy. The formation of hydrogen bonded complexes was investigated at various temperatures using FTIR spectroscopy. Molecular ordering was studied by X-ray diffraction as a function of temperature and composition both for the crystalline and the mesomorphic states.

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