Pressure Dependence of the Nematic-to-Isotropic Transition in the Lyotropic Liquid Crystal Cesium Perfluoro-Octanoate

Abstract
We report light-scattering measurements under pressures up to 1000 bars of nematic short-range order in the isotropic phase of the lyotropic liquid-crystal system cesium perfluoro-octanoate and water. The nematic-to-isotropic transition temperature is a nonlinear function of pressure which changes strongly with concentration and dTNIdp is from 10 to 100 times smaller than in typical thermotropic nematics. We also find the bare correlation length in the isotropic phase to be 12.5 ± 2 Å.