Intramolecular hydrogen-bonding affecting dioxygen binding to cobalt(II) porphyrins
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 316-318
- https://doi.org/10.1039/c39860000316
Abstract
Dioxygen binding to CoII 1-naphthyl porphyrins substituted with amido, carboxy, and hydroxymethyl groups at the 8-naphthyl position displayed significant enhancements in O2 affinity which correlates well with H-bond strength.Keywords
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