Physicochemical studies of some cyclic carbonates. Part V. The alkaline hydrolysis of vinylene carbonate

1 January 1966

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic

p. 5-6
https://doi.org/10.1039/j29660000005

Abstract

The dielectric constant and dipole moment of vinylene carbonate have been measured, and the alkaline hydrolysis of this ester in dilute aqueous ethanol has been studied. This reaction is first-order in ester concentration, and k_r= 0·067 sec.^–1 at 25°. A mechanism for the hydrolysis is proposed.

Keywords

CYCLIC
DIPOLE
ETHANOL
SEC
AQUEOUS
DILUTE
DIELECTRIC
VINYLENE
PHYSICOCHEMICAL

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