Anomalous facile carbon–nitrogen bond cleavage in novel diastereoisomers of the ethylenediaminetetra-3-propionatochromate(III) ion
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 613-615
- https://doi.org/10.1039/c39880000613
Abstract
Diastereoisomers of three ethylenediaminetetra-3-propionatochromate(III) ions and the (S)-propane-1,2-diamine analogues, have been synthesized and characterized by 2H n.m.r. and circular dichroism (c.d.) spectroscopy; a facile C–N bond cleavage occurs during decomposition on heating at 60 °C, and this process was followed by spectroscopy.Keywords
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