Dependence of dehydrogenation of amines towards coordination geometry: oxidation products of tricyano[di(2-pyridylmethyl)amine]ferrate(II) from mer and fac isomers
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 2015-2016
- https://doi.org/10.1039/c39940002015
Abstract
Two geometrical isomers, mer- and fac-tricyano[di(2-pyridylmethyl)amine]ferrate(II) give the iron(II) complex with dehydrogenated ligand and iron(III) complex with intact ligand, respectively, upon oxidation with (NH4)2SO4 or H2O2 at neutral pH, which is confirmed by electrochemical measurements.Keywords
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