Preparation and Properties of Metal Complexes with TTP-Dithiolate Ligands
- 1 January 2002
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 379 (1) , 71-76
- https://doi.org/10.1080/713738644
Abstract
Several copper and platinum complexes with TTP (2,5-bis(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene) dithiolato ligands, Cu(ttpdt) 2 ( 1 ) and Pt(ttpdt)(bpy) ( 2 ), have been prepared. The tetrakis(ethylthio) and tetrakis(hexylthio) derivatives of neutral Cu(ttpdt) 2 showed relatively high conductivity of rt =10 m 2 S cm m 1 on compressed pellets. On the other hand, radical cation salts of 1 and 2 exhibited moderate conductivity of rt =10 m 2 m 10 m 4 S cm m 1 . dithiolene complex tetrathiapentalene cyclic voltammetry electrical conductivityKeywords
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