A General Approach to Aza‐Heterocycles by Means of Domino Sequences Driven by Hydroformylation

Abstract
The development of hydroformylative domino reactions of easily accessible vinyl acetamides is described. Extremely regioselective hydroformylation of terminal double bounds provides a transient N‐acyliminium that can be trapped by various nucleophiles to give several aza‐heterocylic scaffolds in a diastereoselective manner.

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