Electron spin resonance of the boron trimer
- 15 August 1991
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 95 (4) , 3009-3011
- https://doi.org/10.1063/1.460903
Abstract
The 11B3 molecule, observed in neon, argon, and krypton matrices at 4 K has D3h symmetry and a 2A′1 ground state. the isotropic hyperfine tensor indicates ∼15% s hybridization of the in-plane p-bonded orbital of the unpaired spin and rapid rotation of the trimer in the solids.Keywords
This publication has 11 references indexed in Scilit:
- Electronic energies, geometries, and vibrational frequencies of the ground and low-lying excited states of the boron trimerThe Journal of Chemical Physics, 1991
- An ab initio CI determination of the low-lying electronic states of B3Chemical Physics Letters, 1989
- Collision-induced dissociation and ab initio studies of boron cluster ions: determination of structures and stabilitiesThe Journal of Physical Chemistry, 1988
- Electron spin resonance of the C6, C8, and C1 moleculesThe Journal of Chemical Physics, 1988
- Generalization of Heisenberg Hamiltonians to non half-filled bands : a magneto-angular effective Hamiltonian for boron clustersJournal de Physique, 1987
- Electron spin resonance spectra of the aluminum trimer in hydrocarbon matrixes: a quartet 4A2 stateThe Journal of Physical Chemistry, 1985
- ESR of pseudorotating 6Li3 and 7Li3The Journal of Chemical Physics, 1983
- The dynamic Jahn–Teller effect in the electronic ground state of Li3. An a b i n i t i o calculation of the BO hypersurface and the lowest vibronic states of Li3The Journal of Chemical Physics, 1978
- Atomic parameters for paramagnetic resonance dataJournal of Magnetic Resonance (1969), 1978
- Second-Order Splittings in the ESR Spectra of Organic RadicalsThe Journal of Chemical Physics, 1962