Reversible P–C bond formation for saturated α-aminophosphine ligands in solution: stabilization by coordination to Cu(I)
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 23 (6) , 581-583
- https://doi.org/10.1039/a902783a
Abstract
The saturated α-aminophosphine ligands containing a secondary amine function Ph2PCH(R′)NHR″ establish a solution equilibrium with Ph2PH and R′CH2NR″ and are stabilized by electron-withdrawing substituents R′ and R″ and by coordination of the phosphorous donor to Cu(I).Keywords
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