Photo-induced tautomerisation of methyltrioxorhenium(vii): the intermediate in olefin metathesis?
- 1 January 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 67-68
- https://doi.org/10.1039/a907908d
Abstract
Matrix-isolated [CH3ReO3] tautomerises to [H2CRe(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.This publication has 0 references indexed in Scilit: