The preparation and X-ray structure of Pt(Se3N)Cl(PMe2Ph)
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 408-409
- https://doi.org/10.1039/c39890000408
Abstract
Reaction of Se4N4 with [PtCl2(PMe2Ph)]2, in refluxing CHCl3, results in Pt(Se3N)Cl(PMe2Ph), (1), the first example of a metal selenium–nitrogen complex, which contains the bidentate, selenium-bound Se3N– ligand; from X-ray crystallography (1) is square planar with a bidentate Se3N– ligand co-ordinated through two selenium atoms.Keywords
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