On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 646-647
- https://doi.org/10.1039/c39850000646
Abstract
Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.Keywords
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