REPARATION OF HOMOLEPTIC t-BUTYL ISOCYANIDE COMPLEX OF Mo(0) AND REACTIONS WITH ALKYL HALIDES. MOLECULAR STRUCTURE OF [Mo(t-BuN=CCH2Ph) (t-BuNC)5]Br
- 5 July 1982
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 11 (7) , 1017-1020
- https://doi.org/10.1246/cl.1982.1017
Abstract
Hexakis(t-butyl isocyanide)molybdenum(0) was prepared and reacted with alkyl halides to give η2-iminoacyl Mo(II) complexes. An X-ray structural study of the product, [Mo(t-BuN=CCH2Ph)(t-BuNC)5]Br revealed a distorted octahedral molecular structure, regarding the iminoacyl ligand as an unidentate ligand. An intensive bending (137°) of the t-butyl isocyanide trans to the η2-iminoacyl ligand was salient.This publication has 10 references indexed in Scilit:
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