Immobilization and chelation of metal complexes with bifunctional phosphine ligands: a solid-state NMR study

Abstract
29 Si CP MAS NMR shows that a transition-metal complex with two bifunctional phosphine ligands such as (CO)2Ni[PPh2(C6H4)SiMe2OEt]2, when attached to a silica surface according to a commonly used procedure, is mainly anchored by just one ligand.

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