Intermolecular interactions in water + acetonitrile mixtures : Evidence from the composition variation of solvent polarity parameters
- 1 January 1981
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 34 (5) , 943-947
- https://doi.org/10.1071/ch9810943
Abstract
The dependence on composition of the polarity of H2O+MeCN mixtures has been determined from measurements of the empirical solvent polarity parameter ET. ET has been found to vary with composition in a similar fashion to that which has been reported previously for most other H2O+non-electrolyte mixtures for which ET data are available. The variation of ET with composition is interpreted in terms of the Naberukhin-Rogov structural model for H2O+nonelectrolyte mixtures.Keywords
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