Abstract
The mean-field phase diagram of the cholesteric–smectic-A–smectic-C* (N*Sm-A–Sm-C*) point is derived within the framework of the chiral Chen-Lubensky model. We show that on the Sm-C* side of the phase diagram, one or two additional twist-grain-boundary (TGB) (or chiral-smectic) phases will occur. These additional chiral-smectic phases, the TGBC and TGBC* phases, are highly dislocated versions of smectic-C and smectic-C* phases, respectively. According to the de Gennes superconductor analogy, the grain-boundary phase which occurred on the smectic-A side of the phase diagram (known as the TGBA or chiral Sm-A* phase) is the analog of the Abrikosov vortex lattice in type-II superconductors. However, the TGBC and TGBC* phases would correspond to Abrikosov vortex lattices in a hypothetical superconductor where the Ginzburg parameter κ is negative and the photon has Bose condensed. These additional phases are predicted to occur near the recently observed N*Sm-A*Sm-C* multicritical point. We discuss the N* TGBC, TGBA TGBC, and TGBA TGBC* phase transitions. Because of the twist, the XY-like Sm-A–Sm-C is (usually) replaced by the Ising-like TGBA TGBC. However, if the Sm-C* helicoidal pitch length is somewhat smaller than the cholesteric pitch length, then the TGBA TGBC transition would be replaced by the TGBA TGBC* transition.