Nonlinear rupture of thin free liquid films
- 1 April 1986
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 84 (7) , 4043-4048
- https://doi.org/10.1063/1.450065
Abstract
We study nonlinear effects on film rupture by investigating the stability of a viscous free film to finite amplitude disturbances. Until now, theoretical results were obtained through a linear stability analysis for infinitesimal perturbations, which is only valid for a short time since disturbances grow to finite size at rupture. The liquid film considered is uncharged, nondraining, and laterally unbounded. The dynamics of the film is described by the Navier–Stokes equations where attractive van der Waals forces are operative, with suitable boundary conditions at the two surfaces (in the particular case of tangentially immobile surfaces). A nonlinear evolution equation describing the variation of the film thickness along the lateral space dimension, is derived for the squeezing mode which is characterized by symmetrical surface waves. This highly nonlinear partial differential equation is solved numerically and rupture characteristics are predicted and compared to experiments. It is shown that the nonlinearities significantly accelerate the rupture process.Keywords
This publication has 17 references indexed in Scilit:
- A theory of coalescencePublished by Elsevier ,2001
- Repulsive hydration forces between charged lipidic bilayers. A linear stability analysisColloids and Surfaces, 1984
- Spectral analysis of light scattered by liquid films. I. General considerationsThe Journal of Chemical Physics, 1984
- The role of repulsive hydration forces on the stability of aqueous black films. Application to vesicle fusionJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1984
- Electrohydrodynamic stability of unsymmetrical aqueous films. Application to membrane–membrane interactionsJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1983
- Membrane fusion and molecular segregation in phospholipid vesiclesBiochimica et Biophysica Acta (BBA) - Biomembranes, 1974
- Spontaneous rupture of thin liquid filmsJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1974
- Dynamics of Free Liquid FilmsThe Journal of Chemical Physics, 1968
- Thin liquid filmsAdvances in Colloid and Interface Science, 1967
- Possible mechanism for the spontaneous rupture of thin, free liquid filmsDiscussions of the Faraday Society, 1966