Reactions of some metalloporphyrin and metallochlorin π-cation radicals with nitrite
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 772-773
- https://doi.org/10.1039/c39740000772
Abstract
Treatment of π-cation radicals of magnesium(II) and cadmium(II) octa-alkylporphyrins with sodium nitrite affords good yields of meso-mononitroporphyrins after demetallation; with zinc(II)trans-octaethylchlorin, meso-substitution occurs adjacent to the partially reduced ring.Keywords
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