Dioscorone. Regioselective Oxxmercuration of 2-Azabicyclo[2. 2]oct-5-ene
- 1 January 1972
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 2 (4) , 211-214
- https://doi.org/10.1080/00397917208081769
Abstract
Oxymercuration of 2-azabicylo[2.2.2]oct-5-ane 1 occurs regioselectively to give a50:50 mixture of 5-syn-and 5-anti-isoquinculidinols 2 which can be converted to dioscorone 5.Keywords
This publication has 3 references indexed in Scilit:
- The Oxymercuration-Demercuration of Representative Olefins. A Convenient, Mild Procedure for the Markovnikov Hydration of the Carbon-Carbon Double BondJournal of the American Chemical Society, 1967
- Oxymercuration of Olefins. II. cis- and trans-Oxymercuration of Bicyclo [2.2.2]oct-2-eneJournal of the American Chemical Society, 1964
- 928. An alkaloid of dioscorea hispida, dennstedt. Part VIII. Synthesis and resolution of 2-methyl-5-oxoisoquinuclidine and synthesis of dioscorineJournal of the Chemical Society, 1964