Ein erster Schritt in Richtung auf die Phosphor‐Analoga von Polythiophenen
- 1 June 1990
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 102 (6) , 672-675
- https://doi.org/10.1002/ange.19901020609
Abstract
Tetramerisierung unter α‐Thienylwanderung zu 2 und anschließende Spaltung der P‐P‐Bindungen mit Natrium machte aus 1 ein zu α‐Sexithienyl isoelektronisches Biphospholyl‐Dianion zugänglich. Seine weitere Derivatisierung ergab einen W‐ und einen Mo‐Komplex, deren Röntgenstrukturanalysen wichtige Hinweise auf die Elektronenstruktur der Kette lieferten. magnified imageKeywords
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