Oxidation of benzylic hydrocarbons with benzeneseleninic anhydride and related reactions
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2179-2185
- https://doi.org/10.1039/p19820002179
Abstract
The use of benzeneseleninic anhydride as a new side-chain oxidant for a variety of aromatic and heteroaromatic hydrocarbons has been investigated. The oxidation normally proceeds well for simple substrates, neat or in chlorobenzene solution at 100–130 °C. In examples where the aromatic rings are susceptible towards electrophilic attack selenated compounds are usually formed as the major by-products.Keywords
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