Boron Trifluoride-Catalyzed Rearrangement of 2-Aryloxytetrahydropyrans: A New Entry to C-Arylglycosidation

1 January 1988

journal article
research article
Published by Georg Thieme Verlag KG in Synthesis

Vol. 1988 (12) , 1005-1007
https://doi.org/10.1055/s-1988-27788

Abstract

Treatment of 2-aryloxytetrahydropyrans with boron trifluoride afforded 2-aryltetrahydropyrans via rearrangement in good yield. Aryl O-glycopyranosides were converted into the corresponding C-glycopyranosides by the same procedure.

Keywords

TREATMENT
ARYLOXYTETRAHYDROPYRANS
TRIFLUORIDE CATALYZED
CATALYZED REARRANGEMENT
PROCEDURE
ARYLTETRAHYDROPYRANS
CONVERTED
GOOD

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