Axis Switching in the Transition of HCO: Determination of Molecular Geometry

Abstract
The band systems of HCO and DCO have been reinvestigated with higher resolving power than in earlier work. Some weak lines have been assigned to K′ = 0 – K″ = 0 and K′ = 0 – K″ = 2 subbands; these lines derive their intensity from axis switching. The new data give values for the A rotational constants of HCO and DCO and permit a more reliable determination of the ground state geometry, viz, r0(CH) = 1.125(5) Å, r0(CO) = 1.175(1) Å, . The sign of the spin–rotation constant εaa has been shown to be positive.