Structural properties of the superconductor LaBa2Cu3yO7z in the solid solution system La1+xBa2xCu3yO7z

Abstract
We present time-of-flight (TOF) neutron-powder-diffraction results of four samples in the solid-solution orthorhombic La1+x Ba2x Cu3y O7z system. The data for all of the samples were taken at room temperature. The average crystal structures of LaBa2 Cu2.90 O6.82 (Tc=45 K), La1.56 Ba1.44 Cu2.86 BO6.98 (nonsuperconductor), and the impurity-free LaBa2 Cu3 O6.85 (Tc=93 K) were refined by the Rietveld analysis which includes the refinement of the occupancies of the La and/or Ba atoms. The remaining sample was imhomogeneous LaBa2 Cu3y O7z (Tc=85 K).