Reversible oxygenation of metal complexes: electronic and steric factors
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1080-1081
- https://doi.org/10.1039/c29710001080
Abstract
The rates of oxygen addition to trans-[IrCl(CO)-(R3P)2](R3P = tertiary phosphine) and the stability of the resulting dioxygen adducts, [O2IrCl(CO)(R3P)2], increase with increasing basicity of the substituent R, provided the substituents have comparable structures; the geometry of R exerts a profound effect on the dynamics of these reactions.Keywords
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