A route, via tetraquinane, to the 5-8-5 carbocyclic nucleus of fusicoccins and ophiobolins
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1319-1321
- https://doi.org/10.1039/c39860001319
Abstract
Short, stereoselective syntheses of dicyclopenta[a,d]cyclo-octane-based diones (14) and (+)-(22)via a 5-5-5-5→5-8-5 strategy are reported; our approach constitutes an effective methodology for constructing fusicoccane and ophiobolane-type natural products.Keywords
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