Enthalpy and volume changes on mixing diethylene glycol di-n-alkyl ethers with diethylene glycol dimethyl ether or n-alkanes

Abstract
Enthalpy and volume changes on mixing diethylene glycol di-n-alkyl ethers (alkyl–oxyethylene–alkyl triblock oligomers) with either diethylene glycol dimethyl ether [oligo(oxyethylene)] or the C12, C14 and C16 n-alkanes have been measured at 31 °C. The results for these pseudo-binary mixtures are compared with those for binary systems, i.e. oligo-(oxyethylene)s + n-alkanes.

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