33S nuclear quadrupole coupling in the rotational spectra of (1000) and (0001) carbonyl sulfide: vibrational excitation in a D.C. glow discharge
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 88 (20) , 3119-3120
- https://doi.org/10.1039/ft9928803119
Abstract
Rotational spectra have been observed in the vibrational states (1000) and (0001) of the isotopomer 16012C33S in an isotopically normal sample of carbonyl sulfide by incorporating a D.C. glow discharge into a pulsed-nozzle, Fourier-transform microwave spectrometer. The values determined for the 33S nuclear quadrupole coupling constants are χv(33S)=–29.7221(18) and –29.1200(12) MHz for the states (1000) and (0001), respectively.Keywords
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