Universality in the Critical Broadening of Spectral Lines in Simple Fluids

Abstract
Nonlinear mode-coupling hydrodynamics is used to study the broadening of spectral lines near a liquid-gas critical point. The critical contribution to the line shape is given by a universal line-shape function. For values of ε=|(TTc)Tc| which are not too small, the line assumes a Lorentzian form and the width Γ^ increases as εs with the critical exponent s=γ+ν=0.607. Very close to the critical point the line changes into a Levy distribution [the Fourier transform of exp(tr) where r=(3η)2] and the line shape becomes independent of ε (s=0).