Abstract
The mechanism of reversible radiation-induced structural transformations in vitreous As2S3 is studied using IR Fourier-spectroscopy technique. It is established that observed effects are associated with destruction-polymerization processes (transformations of the products containing homopolar S-S and heteropolar As-S bonds into the products on the heteropolar As-S and homopolar As-As bonds basis respectively) in vitreous matrix which lead to the stabilization of (As4 +, S1) coordination defects.

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