v-representability for systems with low degeneracy
- 1 September 1991
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 44 (5) , 2816-2822
- https://doi.org/10.1103/physreva.44.2816
Abstract
We consider the v-representability of the particle density for a noninteracting system of spinless fermions by introducing the idea of proper order of a set of energy levels. It is shown that if (λ), (λ), and (λ) are three energy levels associated with some local potential (r) that is a continuous function of λ=(,,) over all possible points λ, where is the occupation number of the ith state and M=++ is the total number of particles distributed over the three levels, then there must be at least one λ for which the three levels are in so-called proper order, in which the levels below the highest occupied level are filled. This result provides a basis for the proof of ensemble v-representability of some N-particle density for which the ground-state degeneracy of the system is no more than three. As examples, three- and two-dimensional central systems are examined, and an N-particle central density is shown to be ensemble v-representable for small N (N≤14 and N≤9 for three- and two-dimensional cases, respectively). The implications for density-functional theory are discussed.
Keywords
This publication has 10 references indexed in Scilit:
- v-representability for systems of a few fermionsPhysical Review A, 1991
- Effective potentials in density-functional theoryPhysical Review B, 1988
- Density-functional theory for two noninteracting spinless fermionsPhysical Review B, 1986
- Extrema of the density functional for the energy: Excited states from the ground-state theoryPhysical Review B, 1985
- -Representability and Density Functional TheoryPhysical Review Letters, 1983
- Hohenberg-Kohn theorem and non-V-representable densitiesPhysica A: Statistical Mechanics and its Applications, 1983
- Basic TopologyPublished by Springer Nature ,1983
- Electron densities in search of HamiltoniansPhysical Review A, 1982
- Self-Consistent Equations Including Exchange and Correlation EffectsPhysical Review B, 1965
- Inhomogeneous Electron GasPhysical Review B, 1964