Diastereoselective Addition of Silyl Enol Ether to Chiral Imines and 1,3-Oxazolidines Using a Lewis Acid

1 May 1998

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1998 (5) , 489-490
https://doi.org/10.1055/s-1998-1718

Abstract

The Lewis acid promoted reaction of silyl enol ether to chiral imines and 1,3-oxazolidines derived from (R)-phenylglycinol afforded with good diastereoselectivity the (R,R)-β-amino ester derivatives from the imines, and the (R,S)-β-amino ester derivatives from the 1,3-oxazolidines.

Keywords

DIASTEREOSELECTIVE ADDITION REACTION
SILYL ENOL ETHER
LEWIS ACID
CHIRAL IMINE
CHIRAL 1
3-OXAZOLIDINE
(R)-PHENYLGLYCINOL
Β-AMINO ESTER

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