NOTIZEN: Hinweise auf die Existenz von Trimethylsilylmagnesiumverbindungen / Evidence for the Existence of Trimethylsilylmagnesium Compounds
Open Access
- 1 February 1976
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 31 (2) , 281-282
- https://doi.org/10.1515/znb-1976-0232
Abstract
Trimethylchlorosilane reacts with magnesium in hexamethylphosphortriamide yielding hexamethyldisilane. An organosilylmagnesium compound is proposed as reactive intermediate in this reaction. Further evidence for the existence of trimethylsilylmagnesium compounds could be obtained in the reaction of trimethylchlorosilane with highly reactive magnesium in tetrahydrofurane as solvent.Keywords
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