Mechanistic Study of the Ru₃(CO)₁₂/Tetraalkylammonium Chloride Catalyzed Carbonylation Reactions of Nitroarenes to Carbamates and Ureas: A Completely Revised Picture

This publication has 36 references indexed in Scilit:

• Radical Processes in the Reduction of Nitrobenzene Promoted by Iron Carbonyl Clusters. X-ray Crystal Structures of [Fe3(CO)9(.mu.3-NPh)]2-, [HFe3(CO)9(.mu.3-NPh)]-, and the Radical Anion [Fe3(CO)11]-.bul.
  Organometallics, 1995
• Mechanistic Study of the Carbonylation of Nitrobenzene Catalyzed by the [Rh(CO)4]-/Nitrogen Base System. X-ray Structure of [cyclic] [PPN][Rh(CO)2ON(C6H3Cl2)C(O)O]
  Organometallics, 1994
• Homogeneous Catalytic Carbonylation of Nitroaromatics. 7. Transesterification and an Intramolecular Ligand-Hopping Mechanism for Isomerization in the Bis(methoxycarbonyl) Complex Ru(Ph2PCH2CH2PPh2)(CO)2[C(O)OCH3]2
  Organometallics, 1994
• Homogeneous catalytic carbonylation of nitroaromatics. 6. Synthesis and structure of two bis(carbamoyl) complexes of ruthenium
  Inorganic Chemistry, 1994
• Homogeneous catalytic carbonylation of nitroaromatics. 5. Kinetics and mechanism of aniline and carbamate formation using ruthenium complex Ru(Ph2PCH2CH2PPh2)(CO)3
  Journal of the American Chemical Society, 1992
• Halide-promoted carbonylation of the imido ligand in osmium cluster Os3(.mu.3-NPh)(CO)10
  Organometallics, 1992
• Homogeneous catalytic carbonylation of nitroaromatics. 2. Characterization of two intermediates, Ru[C(O)N(Ar)O][Ph2P(CH2)2PPh2](CO)2 and Ru[C(O)OCH3]2[Ph2P(CH2)2PPh2](CO)2, and evidence for the carbamate-forming step
  Journal of the American Chemical Society, 1991
• Ruthenium carbonyl catalyzed reductive carbonylation of aromatic nitro compounds. A selective route to carbamates
  The Journal of Organic Chemistry, 1988
• Reversible Interconversion of C-C and C-N Multiple Bond Systems on Clusters
  Angewandte Chemie International Edition in English, 1986
• Kinetics and mechanism of oxygen atom transfer from nitro compounds mediated by nickel(0) complexes
  Inorganic Chemistry, 1980