Oxygen-17 n.m.r. study of linkage isomerization in nitritopentaamminecobalt(III): evidence for intramolecular oxygen exchange

Abstract
17 O N.m.r. spectroscopy of specifically labelled CO(NH3)5(ONO)2+ shows that spontaneous intramolecular O-to-O exchange in the nitrite ligand occurs at a rate comparable to that of the spontaneous O-to-N isomerization.

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