Enantioselective radical cyclization controlled by a chiral aluminium reagent
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 579-580
- https://doi.org/10.1039/cc9960000579
Abstract
Free radical cyclization of cyclohexyl 8-iodo-nona-2,8-dienoate in the presence of a chiral aluminium reagent, prepared from (R)-3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol and Me3Al, gives optically active 2-(2-methylenecyclopentyl)acetate in 63% yield and 46% ee.Keywords
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