A carbon-13 nuclear magnetic resonance study of (arene)(cyclopentadienyl)iron salts
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 529-534
- https://doi.org/10.1039/dt9810000529
Abstract
Carbon-13 n.m.r. data are presented for the complexes [Fe(η-C5H5)(η-C6H5X)][PF6] where X is one of 17 substituents. The results are discussed in terms of current theories and are compared with data for other related transition-metal systems. The chemical shifts are qualitatively interpreted by consideration of the ligand–metal interactions. Spectral data are also given for 17 polysubstituted arene complexes of the type [Fe(η-C5H5)(η-arene)][PF6].Keywords
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