Novel zirconium complexes of amine bis(phenolate) ligands. Remarkable reactivity in polymerization of hex-1-ene due to an extra donor arm
- 22 February 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 379-380
- https://doi.org/10.1039/b000396o
Abstract
Zirconium complexes of two dianionic amine bis(phenolate) ligands have been synthesized, their X-ray structures solved, and their activity as hex-1-ene polymerization catalysts studied; upon treatment with B(C6F5)3, an octahedral [ONNO]Zr(CH2Ph)2 complex, having an extra N-donor group on a side arm, shows exceptionally high polymerization activity and yields a high molecular weight poly(hex-1-ene), whereas a related pentacoordinate [ONO]Zr(CH2Ph)2 complex, having no extra donor group, shows only poor activity as a polymerization catalyst.Keywords
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