Umpolung in allylic phosphonates. Regio- and stereo-selective synthesis of (E)-γ-amino-α,β-unsaturated phosphonates by palladium-catalysed reaction of allylic acetoxy phosphonates
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1318-1319
- https://doi.org/10.1039/c39870001318
Abstract
γ-Amino-α,β-unsaturated phosphonates have been synthesized regio- and stereo-selectively in high yield by the reaction of allylic α-acetoxy phosphonates with secondary amines catalysed by palladium.Keywords
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