“Counter” Phase Transfer Catalysis by Water-soluble Phosphine Complexes. Catalytic Reduction of Allyl Chlorides and Acetates with Sodium Formate in Two-phase Systems
- 5 September 1986
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (9) , 1463-1466
- https://doi.org/10.1246/cl.1986.1463
Abstract
In the reduction of allyl chlorides and acetates with sodium formate in a heptane-water two-phase system, water-soluble palladium complexes function as a novel type of catalyst which transports the substrate into the aqueous phase and causes it to react with sodium formate.This publication has 3 references indexed in Scilit:
- Inverse phase transfer catalysis. First report of a new class of interfacial reactionsJournal of the American Chemical Society, 1986
- Peculiar kinetics of hydrogenations catalyzed by chlorotris-(sulphonated triphenylphosphine)rhodium(I) in aqueous solutionsJournal of Molecular Catalysis, 1984
- Regio- and stereoselective reductive replacement of allylic oxygen, sulfur, and selenium functional groups by hydride via catalytic activation by palladium(0) complexesThe Journal of Organic Chemistry, 1982