Intramolecular amidoseleniation of N-alkenyl imidates to N-heterocycles
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1837-1843
- https://doi.org/10.1039/p19860001837
Abstract
The reactions of N-alkenyl imidates with benzeneselenenyl chloride and bromide in chloroform at ambient temperature afford pyrrolidine and piperidine derivatives having a phenylseleno moiety in good to excellent yields under neutral conditions. The key step of this new reaction consists of an intramolecular carbon–nitrogen bond formation and a simultaneous carbon–oxygen bond fission.Keywords
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