A Robust New Motif for Supramolecular Construction: The Edge to Edge Aryl C—H···N Dimer
- 1 May 1998
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 313 (1) , 75-83
- https://doi.org/10.1080/10587259808044261
Abstract
The edge to edge aryl C—H···N dimer is a previously unrecognised intermolecular hydrogen bonded lattice packing motif; a search of the Cambridge Structural Database revealing that it is widespread amongst many classes of aromatic nitrogen-containing solids. This weak attractive interaction can be retained throughout crystal engineering studies as typified by the systematic modification of the diquinoline 1 into host-guest compounds formed by its dibromo derivative 2. The latter is a molecule designed to form multimolecular inclusion compounds specifically with small polyhalocarbon guests.Keywords
This publication has 14 references indexed in Scilit:
- Supramolecular Synthons in Crystal Engineering—A New Organic SynthesisAngewandte Chemie International Edition in English, 1995
- 2,4-Diphenylquinoline and its Sterically Hindered Derivative 3-Methyl-2,4-diphenylquinolineActa Crystallographica Section C Crystal Structure Communications, 1995
- Organic Syntheses via Transition Metal Complexes. 79. Aminomethylenation of (.beta.-NH-Aminoethenyl)carbene Complexes of Chromium and TungstenOrganometallics, 1995
- 2-(4-Pentanoyloxyphenyl)-6-pentanoyloxybenzoxazoleActa Crystallographica Section C Crystal Structure Communications, 1994
- C–H ⋯ N mediated hexagonal network in the crystal structure of the 1 : 1 molecular complex 1,3,5-tricyanobenzene–hexamethylbenzeneJournal of the Chemical Society, Chemical Communications, 1993
- The C-H.cntdot..cntdot..cntdot.O hydrogen bond in crystals: what is it?Accounts of Chemical Research, 1991
- The development of versions 3 and 4 of the Cambridge Structural Database SystemJournal of Chemical Information and Computer Sciences, 1991
- Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self‐OrganizationAngewandte Chemie International Edition in English, 1990
- Crystallographic evidence for the existence of CH.cntdot..cntdot..cntdot.O, CH.cntdot..cntdot..cntdot.N and CH.cntdot..cntdot..cntdot.Cl hydrogen bondsJournal of the American Chemical Society, 1982
- Clathrates and molecular inclusion phenomenaChemical Society Reviews, 1978