The interaction of platinumIIchloride with a carbon–carbon σ-bond
- 1 January 1974
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 806-807
- https://doi.org/10.1039/c39740000806
Abstract
In 1H–2H exchange by PtII, cyclobutane shows a remarkably large multiple exchange factor, attributed to interaction between PtII and the C–C bond; tetraphenylcyclobutane is cleaved by PtII to give trans-stilbene while norbornane shows preferential exo exchange.Keywords
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