Vibrational and 1H nuclear magnetic resonance spectra of complexes of gold(I), palladium(II), and platinum(II) containing dimethyl sulphide as a terminal ligand
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 1904-1909
- https://doi.org/10.1039/dt9720001904
Abstract
Vibrational (below 800 cm–1) and 1H n.m.r. spectra of complexes AuXSMe2(X = Cl or Br), Prn 4NMX3SMe2(M = Pd or Pt), Pd2X4(SMe2)2, PtX(SMe2)3BF4, trans-MX2(SMe2)2(including MX = Ptl) and cis-PtCl2(SMe2)2 are reported and assignments proposed. The last can be obtained in a number of solid forms which have markedly different vibrational spectra.Keywords
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