Activation of H2by chlorocarbonylbis(trimethylphosphine)rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe3)2(µ-H)(µ-Cl)RH(PMe3)(CO)
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1185-1187
- https://doi.org/10.1039/c39930001185
Abstract
The oxidative addition of H2 to [RhCl(CO)(PMe3)2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.Keywords
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