Reaction of singlet oxygen with hindered olefins: evidence for a perepoxide intermediate
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 517-518
- https://doi.org/10.1039/c39770000517
Abstract
Isolation, along with expected product, of 1,2-dioxolans of rearranged skeleton from the reaction of singlet oxygen with certain hindered alkenes suggest the intermediacy of a dipolar species such as a perepoxide.Keywords
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