Optical Resolution by Supercritical Fluid Chromatography Using Polysaccharide Derivatives as Chiral Stationary Phases
- 1 August 1992
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 65 (8) , 2286-2288
- https://doi.org/10.1246/bcsj.65.2286
Abstract
The optical resolution of ten racemates by supercritical fluid chromatography (SFC) was investigated using phenylcarbamates of cellulose and amylose and 4-methylbenzoate of cellulose as chiral stationary phases (CSPs) and carbon dioxide–alcohol as a mobile phase. The optical resolving abilities of phenylcarbamates of both cellulose and amylose in SFC were low compared with those in high-performance liquid chromatography (HPLC). However, 4-methylbenzoate of cellulose showed a slightly better optical resolving ability in SFC than in HPLC.Keywords
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