Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amide
- 23 September 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 20,p. 3166-3168
- https://doi.org/10.1039/b412060d
Abstract
‘Selective’ protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3 iPr2-2,6) with H2N(CH2)2OCH3 produced the dimeric species [Ca{(NDippCMe)2CH}{μ-NH(CH2)2OMe}]2, which has been fully characterised in solution and in the solid state.Keywords
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